trans-Acetyldicarbonyl(η5-cyclopentadienyl)[tris(3,5-dimethylphenyl)phosphane-κP]molybdenum(II)

trans-Acetyldicarbonyl(η5-cyclopentadienyl)[tris(3,5-dimethylphenyl)phosphane-κP]molybdenum(II)

The title compound, [Mo(C5H5)(C2H3O)(C24H27P)(CO)2], was prepared by reaction of [Mo(C5H5)(CO)3(CH3)] with tris(3,5-dimethylphenyl)phosphane. The complex exhibits a four-legged piano-stool geometry with trans-disposed acetyl and phosphane ligands. The molecular geometry is nearly identical to that o...

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Bibliographic Details
Main Authors: Matthew T. Whited, Eli J. Ruffer, Jia Zhang, Dominique J. Rabaey, Daron E. Janzen
Format: Article
Language:English
Published: International Union of Crystallography 2017-01-01
Series:IUCrData
Subjects:
crystal structure
phosphine
piano-stool complex
cyclopentadienyl
divalent molybdenum
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2414314617000426

Internet

http://scripts.iucr.org/cgi-bin/paper?S2414314617000426

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