Peracids oxidation of cholesta-5,8-dien-3b-yl acetate
Expoxidation of cholesta-5,8-dien-3b-yl acetate (1) with peracids takes place preferentially at the more highly substituted D8-olefinic double bond to give: (a) with monoperphthalic acid, 8a,9a-epoxycholest-5-en-3b-yl acetate (2) (in 39 % yield) and 9a-hydroxy-5a,6a-epoxycholest-8(14)-en-3b-yl aceta...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Serbian Chemical Society
2000-11-01
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| Series: | Journal of the Serbian Chemical Society |
| Subjects: | |
| Online Access: | http://www.shd.org.yu/HtDocs/SHD/Vol65/No11-Pdf/JSCS11-02.pdf |