Holmium(III) Supermesityl-Imide Complexes Bearing Methylaluminato/Gallato Ligands

Heterobimetallic µ2-imide complexes [Ho(µ2-Nmes*){Al(CH3)4}]2 (1, supermesityl = mes* = C6H2tBu3-2,4,6) and [Ho(µ2-Nmes*){Ga(CH3)4}]2 (2) have been synthesized from homoleptic complexes Ho[M(CH3)4]3 (M = Al, Ga) via deprotonation of H2Nmes* or with K[NH(mes*)] according to a salt metathesis-protonol...

Full description

Bibliographic Details
Main Authors: Dorothea Schädle, Cäcilia Maichle-Mössmer, Karl W. Törnroos, Reiner Anwander
Format: Article
Language:English
Published: MDPI AG 2015-11-01
Series:Inorganics
Subjects:
Online Access:http://www.mdpi.com/2304-6740/3/4/500