(B15c5)BiI3(I2): Molecular Benzo-15-Crown-5―BiI3 Complexes Bridged by Iodine Molecules to Chains

(B15c5)BiI3(I2): Molecular Benzo-15-Crown-5―BiI3 Complexes Bridged by Iodine Molecules to Chains

The reaction of bismuth triiodide with iodine and benzo-15-crown-5 in ethanol/dichloromethane yielded red single crystals of (b15c5)BiI3(I2) (monoclinic, P21/c (no. 14), a = 1376.9(1), b = 1172.7(1), c = 1700.2(2) pm, b = 115.197(6), V = 2484.1(4)·106 pm3, Z = 4). Neutral pseudo-octahedral complexes...

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Bibliographic Details
Main Authors: Christoph Fiolka, Mark Richter, Ingo Pantenburg, Anja-Verena Mudring, Gerd Meyer
Format: Article
Language:English
Published: MDPI AG 2011-10-01
Series:Crystals
Subjects:
bismuth
iodine
crown ether
crystal structure
chemical bonding
Online Access:http://www.mdpi.com/2073-4352/1/4/220

Internet

http://www.mdpi.com/2073-4352/1/4/220

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