Crystal structure of (2,2′-bipyridyl)[2,6-bis(1-butyl-1H-benzimidazol-2-yl)pyridine]chloridoiridium(III) trifluoromethanesulfonate

Crystal structure of (2,2′-bipyridyl)[2,6-bis(1-butyl-1H-benzimidazol-2-yl)pyridine]chloridoiridium(III) trifluoromethanesulfonate

The title complex compound, [Ir(C27H29N5)Cl(C10H8N2)](CF3SO3)2, was synthesized for a study of iridium(III)/periodate redox systems in water. The coordination geometry of the complex can be best described as distorted octahedral, with an r.m.s. deviation of 8.8 (8)% from ideal octahedral rectangular...

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Bibliographic Details
Main Authors: Victoria I. Smith, Mohammad Nozari, Matthias Zeller, Anthony W. Addison
Format: Article
Language:English
Published: International Union of Crystallography 2017-02-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
iridium complex
2,6-bis(N-butylbenzimidazol-2′-yl)pyridine
2,2′-bipyridine
π–π interactions
Online Access:http://scripts.iucr.org/cgi-bin/paper?S205698901700010X

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http://scripts.iucr.org/cgi-bin/paper?S205698901700010X

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