Revealing the electron driven mechanism in metal catalyzed Kumada cross coupling reaction

Revealing the electron driven mechanism in metal catalyzed Kumada cross coupling reaction

Abstract The electron motion mechanism of the metal-catalyzed Kumada cross-coupling reaction, which synthesizes biphenyl from chlorobenzene and phenylmagnesium chloride (a Grignard reagent) using a palladium (Pd) complex with an auxiliary phosphine ligand, is elucidated. This analysis is grounded in...

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Bibliografski detalji
Glavni autori: Noriyuki Takai, Takuro Tsutsumi, Kenichiro Saita, Tetsuya Taketsugu, Takao Tsuneda
Format: Članak
Jezik:English
Izdano: Nature Portfolio 2025-02-01
Serija:Scientific Reports
Teme:
Cross-coupling reaction
Metal complex reaction
Electronic theory
Grignard reagent
Density functional theory
Orbital energy
Online pristup:https://doi.org/10.1038/s41598-025-88207-w

Internet

https://doi.org/10.1038/s41598-025-88207-w

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