Residual Entropy, the Third Law and Latent Heat

A novel thermodynamic treatment of residual entropy in crystals, involving the configurational partition function, is suggested, which is consistent with both classical and statistical thermodynamics. It relates residual entropy to the inherent latent heat which would be released upon cooling if the...

Full description

Bibliographic Details
Main Authors: Frank L. Lambert, Evguenii Kozliak
Format: Article
Language:English
Published: MDPI AG 2008-09-01
Series:Entropy
Subjects:
Online Access:http://www.mdpi.com/1099-4300/10/3/274/