Hexakis(dimethyl sulfoxide-κO)nickel(II) bis(2,2-dicyanoethene-1,1-dithiolato-κ2S,S′)nickelate(II)

The reaction of NiCl2·6H2O with sodium 2,2-dicyanoethene-1,1-dithiolate [Na2(i-mnt)] in dimethyl sulfoxide produces the title complex, [Ni(C2H6OS)6][Ni(C4N2S2)2]. There is half each of an [Ni(C2H6OS)6]2− complex anion and an [Ni{(CH3)2SO}6]2+ complex cation in the asymmetr...

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Bibliographic Details
Main Authors: Meiju Niu, Shumei Fan, Guihua Liu
Format: Article
Language:English
Published: International Union of Crystallography 2012-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811053827