Hexakis(dimethyl sulfoxide-κO)nickel(II) bis(2,2-dicyanoethene-1,1-dithiolato-κ2S,S′)nickelate(II)

The reaction of NiCl2·6H2O with sodium 2,2-dicyanoethene-1,1-dithiolate [Na2(i-mnt)] in dimethyl sulfoxide produces the title complex, [Ni(C2H6OS)6][Ni(C4N2S2)2]. There is half each of an [Ni(C2H6OS)6]2− complex anion and an [Ni{(CH3)2SO}6]2+ complex cation in the asymmetr...

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Main Authors: Meiju Niu, Shumei Fan, Guihua Liu
Format: Article
Language:English
Published: International Union of Crystallography 2012-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811053827
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author Meiju Niu
Shumei Fan
Guihua Liu
author_facet Meiju Niu
Shumei Fan
Guihua Liu
author_sort Meiju Niu
collection DOAJ
description The reaction of NiCl2·6H2O with sodium 2,2-dicyanoethene-1,1-dithiolate [Na2(i-mnt)] in dimethyl sulfoxide produces the title complex, [Ni(C2H6OS)6][Ni(C4N2S2)2]. There is half each of an [Ni(C2H6OS)6]2− complex anion and an [Ni{(CH3)2SO}6]2+ complex cation in the asymmetric unit. The i-mnt ligand coordinates in a bidentate manner to the Ni atom in the anion through the two chelating S atoms in an approximate square-planar geometry. The Ni atom in the complex cation has an octahedral coordination environment with six dimethyl sulfoxide molecules as ligands.
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spelling doaj.art-c013511e07054d8c99fd1ba833862dd42022-12-21T19:34:29ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-01-01681m67m6710.1107/S1600536811053827Hexakis(dimethyl sulfoxide-κO)nickel(II) bis(2,2-dicyanoethene-1,1-dithiolato-κ2S,S′)nickelate(II)Meiju NiuShumei FanGuihua LiuThe reaction of NiCl2·6H2O with sodium 2,2-dicyanoethene-1,1-dithiolate [Na2(i-mnt)] in dimethyl sulfoxide produces the title complex, [Ni(C2H6OS)6][Ni(C4N2S2)2]. There is half each of an [Ni(C2H6OS)6]2− complex anion and an [Ni{(CH3)2SO}6]2+ complex cation in the asymmetric unit. The i-mnt ligand coordinates in a bidentate manner to the Ni atom in the anion through the two chelating S atoms in an approximate square-planar geometry. The Ni atom in the complex cation has an octahedral coordination environment with six dimethyl sulfoxide molecules as ligands.http://scripts.iucr.org/cgi-bin/paper?S1600536811053827
spellingShingle Meiju Niu
Shumei Fan
Guihua Liu
Hexakis(dimethyl sulfoxide-κO)nickel(II) bis(2,2-dicyanoethene-1,1-dithiolato-κ2S,S′)nickelate(II)
Acta Crystallographica Section E
title Hexakis(dimethyl sulfoxide-κO)nickel(II) bis(2,2-dicyanoethene-1,1-dithiolato-κ2S,S′)nickelate(II)
title_full Hexakis(dimethyl sulfoxide-κO)nickel(II) bis(2,2-dicyanoethene-1,1-dithiolato-κ2S,S′)nickelate(II)
title_fullStr Hexakis(dimethyl sulfoxide-κO)nickel(II) bis(2,2-dicyanoethene-1,1-dithiolato-κ2S,S′)nickelate(II)
title_full_unstemmed Hexakis(dimethyl sulfoxide-κO)nickel(II) bis(2,2-dicyanoethene-1,1-dithiolato-κ2S,S′)nickelate(II)
title_short Hexakis(dimethyl sulfoxide-κO)nickel(II) bis(2,2-dicyanoethene-1,1-dithiolato-κ2S,S′)nickelate(II)
title_sort hexakis dimethyl sulfoxide amp 954 o nickel ii bis 2 2 dicyanoethene 1 1 dithiolato amp 954 2s s amp 8242 nickelate ii
url http://scripts.iucr.org/cgi-bin/paper?S1600536811053827
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AT shumeifan hexakisdimethylsulfoxideamp954onickeliibis22dicyanoethene11dithiolatoamp9542ssamp8242nickelateii
AT guihualiu hexakisdimethylsulfoxideamp954onickeliibis22dicyanoethene11dithiolatoamp9542ssamp8242nickelateii