Hexakis(dimethyl sulfoxide-κO)nickel(II) bis(2,2-dicyanoethene-1,1-dithiolato-κ2S,S′)nickelate(II)
The reaction of NiCl2·6H2O with sodium 2,2-dicyanoethene-1,1-dithiolate [Na2(i-mnt)] in dimethyl sulfoxide produces the title complex, [Ni(C2H6OS)6][Ni(C4N2S2)2]. There is half each of an [Ni(C2H6OS)6]2− complex anion and an [Ni{(CH3)2SO}6]2+ complex cation in the asymmetr...
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Format: | Article |
Language: | English |
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International Union of Crystallography
2012-01-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811053827 |
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author | Meiju Niu Shumei Fan Guihua Liu |
author_facet | Meiju Niu Shumei Fan Guihua Liu |
author_sort | Meiju Niu |
collection | DOAJ |
description | The reaction of NiCl2·6H2O with sodium 2,2-dicyanoethene-1,1-dithiolate [Na2(i-mnt)] in dimethyl sulfoxide produces the title complex, [Ni(C2H6OS)6][Ni(C4N2S2)2]. There is half each of an [Ni(C2H6OS)6]2− complex anion and an [Ni{(CH3)2SO}6]2+ complex cation in the asymmetric unit. The i-mnt ligand coordinates in a bidentate manner to the Ni atom in the anion through the two chelating S atoms in an approximate square-planar geometry. The Ni atom in the complex cation has an octahedral coordination environment with six dimethyl sulfoxide molecules as ligands. |
first_indexed | 2024-12-20T15:56:03Z |
format | Article |
id | doaj.art-c013511e07054d8c99fd1ba833862dd4 |
institution | Directory Open Access Journal |
issn | 1600-5368 |
language | English |
last_indexed | 2024-12-20T15:56:03Z |
publishDate | 2012-01-01 |
publisher | International Union of Crystallography |
record_format | Article |
series | Acta Crystallographica Section E |
spelling | doaj.art-c013511e07054d8c99fd1ba833862dd42022-12-21T19:34:29ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-01-01681m67m6710.1107/S1600536811053827Hexakis(dimethyl sulfoxide-κO)nickel(II) bis(2,2-dicyanoethene-1,1-dithiolato-κ2S,S′)nickelate(II)Meiju NiuShumei FanGuihua LiuThe reaction of NiCl2·6H2O with sodium 2,2-dicyanoethene-1,1-dithiolate [Na2(i-mnt)] in dimethyl sulfoxide produces the title complex, [Ni(C2H6OS)6][Ni(C4N2S2)2]. There is half each of an [Ni(C2H6OS)6]2− complex anion and an [Ni{(CH3)2SO}6]2+ complex cation in the asymmetric unit. The i-mnt ligand coordinates in a bidentate manner to the Ni atom in the anion through the two chelating S atoms in an approximate square-planar geometry. The Ni atom in the complex cation has an octahedral coordination environment with six dimethyl sulfoxide molecules as ligands.http://scripts.iucr.org/cgi-bin/paper?S1600536811053827 |
spellingShingle | Meiju Niu Shumei Fan Guihua Liu Hexakis(dimethyl sulfoxide-κO)nickel(II) bis(2,2-dicyanoethene-1,1-dithiolato-κ2S,S′)nickelate(II) Acta Crystallographica Section E |
title | Hexakis(dimethyl sulfoxide-κO)nickel(II) bis(2,2-dicyanoethene-1,1-dithiolato-κ2S,S′)nickelate(II) |
title_full | Hexakis(dimethyl sulfoxide-κO)nickel(II) bis(2,2-dicyanoethene-1,1-dithiolato-κ2S,S′)nickelate(II) |
title_fullStr | Hexakis(dimethyl sulfoxide-κO)nickel(II) bis(2,2-dicyanoethene-1,1-dithiolato-κ2S,S′)nickelate(II) |
title_full_unstemmed | Hexakis(dimethyl sulfoxide-κO)nickel(II) bis(2,2-dicyanoethene-1,1-dithiolato-κ2S,S′)nickelate(II) |
title_short | Hexakis(dimethyl sulfoxide-κO)nickel(II) bis(2,2-dicyanoethene-1,1-dithiolato-κ2S,S′)nickelate(II) |
title_sort | hexakis dimethyl sulfoxide amp 954 o nickel ii bis 2 2 dicyanoethene 1 1 dithiolato amp 954 2s s amp 8242 nickelate ii |
url | http://scripts.iucr.org/cgi-bin/paper?S1600536811053827 |
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