A General Synthesis of Cross-Conjugated Enynones through Pd Catalyzed Sonogashira Coupling with Triazine Esters

A General Synthesis of Cross-Conjugated Enynones through Pd Catalyzed Sonogashira Coupling with Triazine Esters

The palladium-catalyzed Sonogashira coupling of α, β-unsaturated acid derivatives offers a diversity-oriented synthetic strategy for cross-conjugated enynones. However, the susceptibility of the unsaturated C-C bonds adjacent to the carbonyl group toward Pd catalysts makes the direct conversion of α...

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Bibliographic Details
Main Authors: Dezhi Lin, Yunfang Liu, Hongyu Yang, Xiao Zhang, Huaming Sun, Yajun Jian, Weiqiang Zhang, Jianming Yang, Ziwei Gao
Format: Article
Language:English
Published: MDPI AG 2023-05-01
Series:Molecules
Subjects:
palladium catalysis
cross-coupling
C-O activation
ketone synthesis
Online Access:https://www.mdpi.com/1420-3049/28/11/4364

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https://www.mdpi.com/1420-3049/28/11/4364

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