Tetraaquabis{μ2-2,7-bis[(2,6-diisopropylphenyl)iminomethyl]naphthalene-1,8-diolato}di-μ3-hydroxido-di-μ2-hydroxido-bis(trimethylphosphine oxide)tetranickel(II)–trimethylphosphine oxide–diethyl ether–water (1/2/2/2)

The title complex, [Ni4(C36H40N2O2)2(OH)4(C3H9OP)2(H2O)4]·2C4H10O·2C3H9OP·2H2O, is centrosymmetric with a central core that can be described as a defect double cubane. The four metal ions in the cluster are held together by four bridging hydroxide groups. Each...

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Bibliographic Details
Main Authors: Tobin J. Marks, Brandon A. Rodriguez, Michael P. Weberski Jr, Massimiliano Delferro
Format: Article
Language:English
Published: International Union of Crystallography 2010-03-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810003697