Tetraaquabis{μ2-2,7-bis[(2,6-diisopropylphenyl)iminomethyl]naphthalene-1,8-diolato}di-μ3-hydroxido-di-μ2-hydroxido-bis(trimethylphosphine oxide)tetranickel(II)–trimethylphosphine oxide–diethyl ether–water (1/2/2/2)
The title complex, [Ni4(C36H40N2O2)2(OH)4(C3H9OP)2(H2O)4]·2C4H10O·2C3H9OP·2H2O, is centrosymmetric with a central core that can be described as a defect double cubane. The four metal ions in the cluster are held together by four bridging hydroxide groups. Each...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-03-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810003697 |
| _version_ | 1818918735838183424 |
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| author | Tobin J. Marks Brandon A. Rodriguez Michael P. Weberski Jr Massimiliano Delferro |
| author_facet | Tobin J. Marks Brandon A. Rodriguez Michael P. Weberski Jr Massimiliano Delferro |
| author_sort | Tobin J. Marks |
| collection | DOAJ |
| description | The title complex, [Ni4(C36H40N2O2)2(OH)4(C3H9OP)2(H2O)4]·2C4H10O·2C3H9OP·2H2O, is centrosymmetric with a central core that can be described as a defect double cubane. The four metal ions in the cluster are held together by four bridging hydroxide groups. Each NiII atom adopts a distorted octahedral geometry. |
| first_indexed | 2024-12-20T00:54:41Z |
| format | Article |
| id | doaj.art-c1698d67864a40f1bd85474563264254 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T00:54:41Z |
| publishDate | 2010-03-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-c1698d67864a40f1bd854745632642542022-12-21T19:59:09ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-03-01663m257m25710.1107/S1600536810003697Tetraaquabis{μ2-2,7-bis[(2,6-diisopropylphenyl)iminomethyl]naphthalene-1,8-diolato}di-μ3-hydroxido-di-μ2-hydroxido-bis(trimethylphosphine oxide)tetranickel(II)–trimethylphosphine oxide–diethyl ether–water (1/2/2/2)Tobin J. MarksBrandon A. RodriguezMichael P. Weberski JrMassimiliano DelferroThe title complex, [Ni4(C36H40N2O2)2(OH)4(C3H9OP)2(H2O)4]·2C4H10O·2C3H9OP·2H2O, is centrosymmetric with a central core that can be described as a defect double cubane. The four metal ions in the cluster are held together by four bridging hydroxide groups. Each NiII atom adopts a distorted octahedral geometry.http://scripts.iucr.org/cgi-bin/paper?S1600536810003697 |
| spellingShingle | Tobin J. Marks Brandon A. Rodriguez Michael P. Weberski Jr Massimiliano Delferro Tetraaquabis{μ2-2,7-bis[(2,6-diisopropylphenyl)iminomethyl]naphthalene-1,8-diolato}di-μ3-hydroxido-di-μ2-hydroxido-bis(trimethylphosphine oxide)tetranickel(II)–trimethylphosphine oxide–diethyl ether–water (1/2/2/2) Acta Crystallographica Section E |
| title | Tetraaquabis{μ2-2,7-bis[(2,6-diisopropylphenyl)iminomethyl]naphthalene-1,8-diolato}di-μ3-hydroxido-di-μ2-hydroxido-bis(trimethylphosphine oxide)tetranickel(II)–trimethylphosphine oxide–diethyl ether–water (1/2/2/2) |
| title_full | Tetraaquabis{μ2-2,7-bis[(2,6-diisopropylphenyl)iminomethyl]naphthalene-1,8-diolato}di-μ3-hydroxido-di-μ2-hydroxido-bis(trimethylphosphine oxide)tetranickel(II)–trimethylphosphine oxide–diethyl ether–water (1/2/2/2) |
| title_fullStr | Tetraaquabis{μ2-2,7-bis[(2,6-diisopropylphenyl)iminomethyl]naphthalene-1,8-diolato}di-μ3-hydroxido-di-μ2-hydroxido-bis(trimethylphosphine oxide)tetranickel(II)–trimethylphosphine oxide–diethyl ether–water (1/2/2/2) |
| title_full_unstemmed | Tetraaquabis{μ2-2,7-bis[(2,6-diisopropylphenyl)iminomethyl]naphthalene-1,8-diolato}di-μ3-hydroxido-di-μ2-hydroxido-bis(trimethylphosphine oxide)tetranickel(II)–trimethylphosphine oxide–diethyl ether–water (1/2/2/2) |
| title_short | Tetraaquabis{μ2-2,7-bis[(2,6-diisopropylphenyl)iminomethyl]naphthalene-1,8-diolato}di-μ3-hydroxido-di-μ2-hydroxido-bis(trimethylphosphine oxide)tetranickel(II)–trimethylphosphine oxide–diethyl ether–water (1/2/2/2) |
| title_sort | tetraaquabis amp 956 2 2 7 bis 2 6 diisopropylphenyl iminomethyl naphthalene 1 8 diolato di amp 956 3 hydroxido di amp 956 2 hydroxido bis trimethylphosphine oxide tetranickel ii amp 8211 trimethylphosphine oxide amp 8211 diethyl ether amp 8211 water 1 2 2 2 |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810003697 |
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