Tetraaquabis{&#956;2-2,7-bis[(2,6-diisopropylphenyl)iminomethyl]naphthalene-1,8-diolato}di-&#956;3-hydroxido-di-&#956;2-hydroxido-bis(trimethylphosphine oxide)tetranickel(II)&#8211;trimethylphosphine oxide&#8211;diethyl ether&#8211;water (1/2/2/2)

Tetraaquabis{&#956;2-2,7-bis[(2,6-diisopropylphenyl)iminomethyl]naphthalene-1,8-diolato}di-&#956;3-hydroxido-di-&#956;2-hydroxido-bis(trimethylphosphine oxide)tetranickel(II)&#8211;trimethylphosphine oxide&#8211;diethyl ether&#8211;water (1/2/2/2)

The title complex, [Ni4(C36H40N2O2)2(OH)4(C3H9OP)2(H2O)4]&#183;2C4H10O&#183;2C3H9OP&#183;2H2O, is centrosymmetric with a central core that can be described as a defect double cubane. The four metal ions in the cluster are held together by four bridging hydroxide groups. Each...

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Bibliographic Details
Main Authors:	Tobin J. Marks, Brandon A. Rodriguez, Michael P. Weberski Jr, Massimiliano Delferro
Format:	Article
Language:	English
Published:	International Union of Crystallography 2010-03-01
Series:	Acta Crystallographica Section E
Online Access:	http://scripts.iucr.org/cgi-bin/paper?S1600536810003697

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