Effects of the Incorporation of Calcium Chloride on the Physical and Oxidative Stability of Filled Hydrogel Particles

In this study, the effects of calcium chloride (CaCl<sub>2</sub>) addition on the physical and oxidative stabilities of filled hydrogel were investigated. The results revealed that CaCl<sub>2</sub> significantly enhanced the particle size, interfacial layer thickness, apparen...

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Main Authors: Xin Li, Chuanai Cao, Dongxue Yuan, Qian Liu, Jinhai Zhao
Format: Article
Language:English
Published: MDPI AG 2022-01-01
Series:Foods
Subjects:
Online Access:https://www.mdpi.com/2304-8158/11/3/278
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author Xin Li
Chuanai Cao
Dongxue Yuan
Qian Liu
Jinhai Zhao
author_facet Xin Li
Chuanai Cao
Dongxue Yuan
Qian Liu
Jinhai Zhao
author_sort Xin Li
collection DOAJ
description In this study, the effects of calcium chloride (CaCl<sub>2</sub>) addition on the physical and oxidative stabilities of filled hydrogel were investigated. The results revealed that CaCl<sub>2</sub> significantly enhanced the particle size, interfacial layer thickness, apparent viscosity, and viscoelastic behavior of filled hydrogels and decreased their light and whiteness values (<i>p</i> < 0.05). This phenomenon was mainly attributed to the strong binding ability between Ca<sup>2+</sup> and protein/pectin mixtures, which were present in the interfacial area or aqueous phase, as verified by cryo-scanning electron microscopy results. Moreover, lower levels of CaCl<sub>2</sub> (2 or 4 mM) significantly enhanced the oxidative stability of filled hydrogels (<i>p</i> < 0.05), particularly at a concentration of 4 mM. However, a higher level of CaCl<sub>2</sub> (6 or 8 mM) resulted in an electrostatic shielding effect, which resulted in the aggregation of multiple droplets and the flocculation of the filled hydrogels, which negatively affected the oxidative stability of filled hydrogels. The findings of this study indicated that appropriate Ca<sup>2+</sup> levels (4 mM) improved the physical and oxidative stability of filled hydrogel, and this finding may provide useful insights for the development of effective delivery systems for specific applications.
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spelling doaj.art-c170e54637ee4bdd992c6630670ebdfe2023-11-23T16:28:17ZengMDPI AGFoods2304-81582022-01-0111327810.3390/foods11030278Effects of the Incorporation of Calcium Chloride on the Physical and Oxidative Stability of Filled Hydrogel ParticlesXin Li0Chuanai Cao1Dongxue Yuan2Qian Liu3Jinhai Zhao4College of Food Science, Northeast Agricultural University, Harbin 150030, ChinaCollege of Food Science, Northeast Agricultural University, Harbin 150030, ChinaCollege of Food Science, Northeast Agricultural University, Harbin 150030, ChinaCollege of Food Science, Northeast Agricultural University, Harbin 150030, ChinaInstitute of Advanced Technology, Heilongjiang Academy of Science, Harbin 150001, ChinaIn this study, the effects of calcium chloride (CaCl<sub>2</sub>) addition on the physical and oxidative stabilities of filled hydrogel were investigated. The results revealed that CaCl<sub>2</sub> significantly enhanced the particle size, interfacial layer thickness, apparent viscosity, and viscoelastic behavior of filled hydrogels and decreased their light and whiteness values (<i>p</i> < 0.05). This phenomenon was mainly attributed to the strong binding ability between Ca<sup>2+</sup> and protein/pectin mixtures, which were present in the interfacial area or aqueous phase, as verified by cryo-scanning electron microscopy results. Moreover, lower levels of CaCl<sub>2</sub> (2 or 4 mM) significantly enhanced the oxidative stability of filled hydrogels (<i>p</i> < 0.05), particularly at a concentration of 4 mM. However, a higher level of CaCl<sub>2</sub> (6 or 8 mM) resulted in an electrostatic shielding effect, which resulted in the aggregation of multiple droplets and the flocculation of the filled hydrogels, which negatively affected the oxidative stability of filled hydrogels. The findings of this study indicated that appropriate Ca<sup>2+</sup> levels (4 mM) improved the physical and oxidative stability of filled hydrogel, and this finding may provide useful insights for the development of effective delivery systems for specific applications.https://www.mdpi.com/2304-8158/11/3/278filled hydrogelCaCl<sub>2</sub>physical stabilityviscoelastic behavioroxidative stability
spellingShingle Xin Li
Chuanai Cao
Dongxue Yuan
Qian Liu
Jinhai Zhao
Effects of the Incorporation of Calcium Chloride on the Physical and Oxidative Stability of Filled Hydrogel Particles
Foods
filled hydrogel
CaCl<sub>2</sub>
physical stability
viscoelastic behavior
oxidative stability
title Effects of the Incorporation of Calcium Chloride on the Physical and Oxidative Stability of Filled Hydrogel Particles
title_full Effects of the Incorporation of Calcium Chloride on the Physical and Oxidative Stability of Filled Hydrogel Particles
title_fullStr Effects of the Incorporation of Calcium Chloride on the Physical and Oxidative Stability of Filled Hydrogel Particles
title_full_unstemmed Effects of the Incorporation of Calcium Chloride on the Physical and Oxidative Stability of Filled Hydrogel Particles
title_short Effects of the Incorporation of Calcium Chloride on the Physical and Oxidative Stability of Filled Hydrogel Particles
title_sort effects of the incorporation of calcium chloride on the physical and oxidative stability of filled hydrogel particles
topic filled hydrogel
CaCl<sub>2</sub>
physical stability
viscoelastic behavior
oxidative stability
url https://www.mdpi.com/2304-8158/11/3/278
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AT dongxueyuan effectsoftheincorporationofcalciumchlorideonthephysicalandoxidativestabilityoffilledhydrogelparticles
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