Chiral 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD)-Catalyzed Stereoselective Ring-Opening Polymerization of <i>rac</i>-Lactide: High Reactivity for Isotactic Enriched Polylactides (PLAs)

Chiral 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD)-Catalyzed Stereoselective Ring-Opening Polymerization of <i>rac</i>-Lactide: High Reactivity for Isotactic Enriched Polylactides (PLAs)

Chiral 4,8-diphenyl-1,5,7-triazabicyclo[4.4.0]dec-5-ene (DiPh-TBD) was synthesized and applied to a ring-opening polymerization of <i>rac</i>-lactide (<i>rac</i>-LA). The chiral DiPh-TBD promoted the synthesis of isotactic enriched polylactides (PLAs) with controlled molecula...

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Bibliographic Details
Main Authors: Qaiser Mahmood, Guangqiang Xu, Li Zhou, Xuanhua Guo, Qinggang Wang
Format: Article
Language:English
Published: MDPI AG 2020-10-01
Series:Polymers
Subjects:
chiral TBD
organocatalyst
ring-opening polymerization
high reactivity
stereoselectivity
Online Access:https://www.mdpi.com/2073-4360/12/10/2365

Internet

https://www.mdpi.com/2073-4360/12/10/2365

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