A Mixed-Valence Tetra-Nuclear Nickel Dithiolene Complex: Synthesis, Crystal Structure, and the Lability of Its Nickel Sulfur Bonds

In this study, by employing a common synthetic protocol, an unusual and unexpected tetra-nuclear nickel dithiolene complex was obtained. The synthesis of the [Ni<sub>4</sub>(ecpdt)<sub>6</sub>]<sup>2−</sup> dianion (ecpdt = (<i>Z</i>)-3-ethoxy-3-oxo-1-...

Full description

Bibliographic Details
Main Authors: Mohsen Ahmadi, Jevy Correia, Nicolas Chrysochos, Carola Schulzke
Format: Article
Language:English
Published: MDPI AG 2020-04-01
Series:Inorganics
Subjects:
Online Access:https://www.mdpi.com/2304-6740/8/4/27