<i>Hetero</i>-Diels-Alder Reactions of In Situ-Generated Azoalkenes with Thioketones; Experimental and Theoretical Studies

<i>Hetero</i>-Diels-Alder Reactions of In Situ-Generated Azoalkenes with Thioketones; Experimental and Theoretical Studies

The <i>hetero</i>-Diels-Alder reactions of in situ-generated azoalkenes with thioketones were shown to offer a straightforward method for an efficient and regioselective synthesis of scarcely known N-substituted 1,3,4-thiadiazine derivatives. The scope of the method was fairly broad, all...

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Bibliographic Details
Main Authors: Grzegorz Mlostoń, Katarzyna Urbaniak, Malwina Sobiecka, Heinz Heimgartner, Ernst-Ulrich Würthwein, Reinhold Zimmer, Dieter Lentz, Hans-Ulrich Reissig
Format: Article
Language:English
Published: MDPI AG 2021-04-01
Series:Molecules
Subjects:
(4 + 2)-cycloadditions
<i>hetero</i>-Diels-Alder reactions
azoalkenes
thioketones
sulfur heterocycles
organic reaction mechanisms
Online Access:https://www.mdpi.com/1420-3049/26/9/2544

Internet

https://www.mdpi.com/1420-3049/26/9/2544

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