Preparation of diamond on GaN using microwave plasma chemical vapor deposition with double-substrate structure

Combining diamond with GaN can significantly improve the heat dissipation performance of GaN-based devices. However, how to avoid the destructive damage to the GaN epi-layer caused by high-temperature hydrogen plasma during the diamond growth is still a problem. This study employed a Si transition l...

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Main Authors: Yurui Wang, Deng Gao, Tong Zhang, Hao Zhang, Yu Zhang, Qiuming Fu, Hongyang Zhao, Zhibin Ma
Format: Article
Language:English
Published: Taylor & Francis Group 2023-12-01
Series:Functional Diamond
Subjects:
Online Access:http://dx.doi.org/10.1080/26941112.2023.2183097
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author Yurui Wang
Deng Gao
Tong Zhang
Hao Zhang
Yu Zhang
Qiuming Fu
Hongyang Zhao
Zhibin Ma
author_facet Yurui Wang
Deng Gao
Tong Zhang
Hao Zhang
Yu Zhang
Qiuming Fu
Hongyang Zhao
Zhibin Ma
author_sort Yurui Wang
collection DOAJ
description Combining diamond with GaN can significantly improve the heat dissipation performance of GaN-based devices. However, how to avoid the destructive damage to the GaN epi-layer caused by high-temperature hydrogen plasma during the diamond growth is still a problem. This study employed a Si transition layer and double-substrate structure microwave plasma chemical vapor deposition (MPCVD) to prepare diamond film on GaN epi-layer. The effects of double-substrate structure on the diamond growth were studied. The microwave plasma parameters of both single-substrate structure and double-substrate structure MPCVD diagnosed by emission spectra were comparatively investigated. It has been found that the microwave plasma energy of double-substrate structure MPCVD is relatively more concentrated and has higher radicals activity, which is beneficial to the diamond growth. The impacts of the Si transition layer on the diamond growth were also investigated. It demonstrates that the Si transition layer can effectively protect the GaN epi-layer from being etched by hydrogen plasma and improve the diamond growth. The relationship between the thickness of the Si transition layer and the diamond growth and the relationship between diamond film thickness and adhesion has been studied in detail.
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spelling doaj.art-c2bfd67d9edb497d95ab312b5b9e83462024-01-04T15:59:10ZengTaylor & Francis GroupFunctional Diamond2694-11202023-12-013110.1080/26941112.2023.21830972183097Preparation of diamond on GaN using microwave plasma chemical vapor deposition with double-substrate structureYurui Wang0Deng Gao1Tong Zhang2Hao Zhang3Yu Zhang4Qiuming Fu5Hongyang Zhao6Zhibin Ma7Hubei Key Laboratory of Plasma Chemistry and Advanced Materials, Department of Materials Science and Engineering, Wuhan Institute of TechnologyHubei Key Laboratory of Plasma Chemistry and Advanced Materials, Department of Materials Science and Engineering, Wuhan Institute of TechnologyHubei Key Laboratory of Plasma Chemistry and Advanced Materials, Department of Materials Science and Engineering, Wuhan Institute of TechnologyHubei Key Laboratory of Plasma Chemistry and Advanced Materials, Department of Materials Science and Engineering, Wuhan Institute of TechnologyHubei Key Laboratory of Plasma Chemistry and Advanced Materials, Department of Materials Science and Engineering, Wuhan Institute of TechnologyHubei Key Laboratory of Plasma Chemistry and Advanced Materials, Department of Materials Science and Engineering, Wuhan Institute of TechnologyHubei Key Laboratory of Plasma Chemistry and Advanced Materials, Department of Materials Science and Engineering, Wuhan Institute of TechnologyHubei Key Laboratory of Plasma Chemistry and Advanced Materials, Department of Materials Science and Engineering, Wuhan Institute of TechnologyCombining diamond with GaN can significantly improve the heat dissipation performance of GaN-based devices. However, how to avoid the destructive damage to the GaN epi-layer caused by high-temperature hydrogen plasma during the diamond growth is still a problem. This study employed a Si transition layer and double-substrate structure microwave plasma chemical vapor deposition (MPCVD) to prepare diamond film on GaN epi-layer. The effects of double-substrate structure on the diamond growth were studied. The microwave plasma parameters of both single-substrate structure and double-substrate structure MPCVD diagnosed by emission spectra were comparatively investigated. It has been found that the microwave plasma energy of double-substrate structure MPCVD is relatively more concentrated and has higher radicals activity, which is beneficial to the diamond growth. The impacts of the Si transition layer on the diamond growth were also investigated. It demonstrates that the Si transition layer can effectively protect the GaN epi-layer from being etched by hydrogen plasma and improve the diamond growth. The relationship between the thickness of the Si transition layer and the diamond growth and the relationship between diamond film thickness and adhesion has been studied in detail.http://dx.doi.org/10.1080/26941112.2023.2183097mpcvdoesdouble-substrate structurediamondgan
spellingShingle Yurui Wang
Deng Gao
Tong Zhang
Hao Zhang
Yu Zhang
Qiuming Fu
Hongyang Zhao
Zhibin Ma
Preparation of diamond on GaN using microwave plasma chemical vapor deposition with double-substrate structure
Functional Diamond
mpcvd
oes
double-substrate structure
diamond
gan
title Preparation of diamond on GaN using microwave plasma chemical vapor deposition with double-substrate structure
title_full Preparation of diamond on GaN using microwave plasma chemical vapor deposition with double-substrate structure
title_fullStr Preparation of diamond on GaN using microwave plasma chemical vapor deposition with double-substrate structure
title_full_unstemmed Preparation of diamond on GaN using microwave plasma chemical vapor deposition with double-substrate structure
title_short Preparation of diamond on GaN using microwave plasma chemical vapor deposition with double-substrate structure
title_sort preparation of diamond on gan using microwave plasma chemical vapor deposition with double substrate structure
topic mpcvd
oes
double-substrate structure
diamond
gan
url http://dx.doi.org/10.1080/26941112.2023.2183097
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