Iminopyridine Ni(II) Catalysts Affording Oily Hyperbranched Ethylene Oligomers and/or Crystalline Polyethylenes Depending on the Reaction Conditions: Possible Role of In Situ Catalyst Structure Modifications
Nickel-based ethylene polymerization catalysts have unique features, being able to produce macromolecules with a variable content of branches, resulting in polymers ranging from semicrystalline plastics to elastomers to hyperbranched amorphous waxes and oils. In addition to Brookhart’s α-diimine cat...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2021-05-01
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| Series: | Macromol |
| Subjects: | |
| Online Access: | https://www.mdpi.com/2673-6209/1/2/10 |