Effects of Spiro-Cyclohexane Substitution of Nitroxyl Biradicals on Dynamic Nuclear Polarization

Effects of Spiro-Cyclohexane Substitution of Nitroxyl Biradicals on Dynamic Nuclear Polarization

Spiro-substituted nitroxyl biradicals are widely used as reagents for dynamic nuclear polarization (DNP), which is especially important for biopolymer research. The main criterion for their applicability as polarizing agents is the value of the spin–spin exchange interaction parameter (<i>J<...

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Bibliographic Details
Main Authors: Nargiz B. Asanbaeva, Larisa Yu. Gurskaya, Yuliya F. Polienko, Tatyana V. Rybalova, Maxim S. Kazantsev, Alexey A. Dmitriev, Nina P. Gritsan, Nadia Haro-Mares, Torsten Gutmann, Gerd Buntkowsky, Evgeny V. Tretyakov, Elena G. Bagryanskaya
Format: Article
Language:English
Published: MDPI AG 2022-05-01
Series:Molecules
Subjects:
EPR
nitroxide
biradical
ferrocene
exchange interaction
DNP
Online Access:https://www.mdpi.com/1420-3049/27/10/3252

Internet

https://www.mdpi.com/1420-3049/27/10/3252

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