(18-Crown-6-κ6O){(trimethylsilyl)[6-(trimethylsilylamino)pyridin-2-yl-κN1]azanido-κN}potassium(I)

(18-Crown-6-κ6O){(trimethylsilyl)[6-(trimethylsilylamino)pyridin-2-yl-κN1]azanido-κN}potassium(I)

The title complex, [K(C11H22N3Si2)(C12H24O6)], contains a single K+ cation coordinated by a monoanionic (6-trimethylsilylaminopyridin-2-yl)(trimethylsilyl)azanide (HL) ligand and an 18-crown-6 ligand. One SiMe3 group in HL is disordered over two positions, with an occupancy ratio of 0.727 (7):0.273 ...

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Bibliographic Details
Main Authors: Sydney E. Toney, Patrick C. Hillesheim, Gary L. Guillet
Format: Article
Language:English
Published: International Union of Crystallography 2016-08-01
Series:IUCrData
Subjects:
crystal structure
potassium complex
trimethylsilylaminopyridine
crown ether
contact ion pair
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2414314616013389

Internet

http://scripts.iucr.org/cgi-bin/paper?S2414314616013389

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