Crystal structure of a Pd4 carbonyl triphenylphosphane cluster [Pd4(CO)5(PPh3)4]·2C4H8O, comparing solvates

Crystal structure of a Pd4 carbonyl triphenylphosphane cluster [Pd4(CO)5(PPh3)4]·2C4H8O, comparing solvates

Attempts to synthesize Au–Pd heterometallic compounds from homonuclear palladium or gold complexes, [Pd(PtBu2)2] and [Au(PPh3)Cl] in a tetrahydrofuran (THF) solution under a CO atmosphere resulted in a homonuclear Pd cluster, namely pentakis(μ-carbonyl-κ2C:C)tetrakis(triphenylphosphane-κP)tetrapalla...

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Bibliographic Details
Main Authors: Koen Robeyns, Christopher Willocq, Bernard Tinant, Michel Devillers, Sophie Hermans
Format: Article
Language:English
Published: International Union of Crystallography 2016-02-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
structure transformation
homonuclear cluster
palladium
gold
crystal structure
Online Access:http://scripts.iucr.org/cgi-bin/paper?S205698901502441X

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http://scripts.iucr.org/cgi-bin/paper?S205698901502441X

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