Thermochemistry of Solution, Solvation, and Hydrogen Bonding of Cyclic Amides in Proton Acceptor and Donor Solvents. Amide Cycle Size Effect

Thermochemistry of Solution, Solvation, and Hydrogen Bonding of Cyclic Amides in Proton Acceptor and Donor Solvents. Amide Cycle Size Effect

In the present work, the thermochemistry of solution, solvation, and hydrogen bonding of cyclic amides in proton acceptor (B) and proton donor (RXH) solvents were studied. The infinite dilution solution enthalpies of δ-valerolactam, <i>N</i>-methylvalerolactam, ε-caprolactam, and <i&g...

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Bibliographic Details
Main Authors: Ilnaz T. Rakipov, Artem A. Petrov, Aydar A. Akhmadiyarov, Artashes A. Khachatrian, Timur A. Mukhametzyanov, Boris N. Solomonov
Format: Article
Language:English
Published: MDPI AG 2021-03-01
Series:Molecules
Subjects:
solution enthalpies
cyclic amides
proton acceptors
proton donors
hydrogen bonding
solution calorimetry
Online Access:https://www.mdpi.com/1420-3049/26/5/1411

Internet

https://www.mdpi.com/1420-3049/26/5/1411

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