Crystal structure of poly[(μ3-thiocyanato-κ3N:S:S)(trimethylphosphine sulfide-κS)copper(I)]

In the title compound, [Cu(NCS)(C3H9PS)]n, the thiocyanate ions bind the CuI atoms covalently, forming infinite –Cu—SCN—Cu– chains parallel to the a axis. Each CuI atom is also coordinated to a trimethylphosphine sulfide group via a Cu—S bond. Two crystallographically independent chains propagate in...

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Bibliographic Details
Main Author: Peter W. R. Corfield
Format: Article
Language:English
Published: International Union of Crystallography 2014-11-01
Series:Acta Crystallographica Section E
Subjects:
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536814021412