Self-Assembly of Supramolecular Architectures Driven by σ-Hole Interactions: A Halogen-Bonded 2D Network Based on a Diiminedibromido Gold(III) Complex and Tribromide Building Blocks

Self-Assembly of Supramolecular Architectures Driven by σ-Hole Interactions: A Halogen-Bonded 2D Network Based on a Diiminedibromido Gold(III) Complex and Tribromide Building Blocks

The reaction of the complex [Au(phen)Br<sub>2</sub>](PF<sub>6</sub>) (phen = 1,10-phenanthroline) with molecular dibromine afforded {[Au(phen)Br<sub>2</sub>](Br<sub>3</sub>)}<sub>∞</sub> (<b>1</b>). Single crystal diffraction an...

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Bibliographic Details
Main Authors: M. Carla Aragoni, M. Francesca Cherchi, Vito Lippolis, Anna Pintus, Enrico Podda, Alexandra M. Z. Slawin, J. Derek Woollins, Massimiliano Arca
Format: Article
Language:English
Published: MDPI AG 2022-09-01
Series:Molecules
Subjects:
gold
supramolecular
halogen bond
sigma-hole
crystallography
DFT
Online Access:https://www.mdpi.com/1420-3049/27/19/6289

Internet

https://www.mdpi.com/1420-3049/27/19/6289

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