Ligand Hydrogenation during Hydroformylation Catalysis Detected by In Situ High-Pressure Infra-Red Spectroscopic Analysis of a Rhodium/Phospholene-Phosphite Catalyst

Ligand Hydrogenation during Hydroformylation Catalysis Detected by In Situ High-Pressure Infra-Red Spectroscopic Analysis of a Rhodium/Phospholene-Phosphite Catalyst

Phospholane-phosphites are known to show highly unusual selectivity towards branched aldehydes in the hydroformylation of terminal alkenes. This paper describes the synthesis of hitherto unknown unsaturated phospholene borane precursors and their conversion to the corresponding phospholene-phosphite...

Full description

Bibliographic Details
Main Authors: José A. Fuentes, Mesfin E. Janka, Aidan P. McKay, David B. Cordes, Alexandra M. Z. Slawin, Tomas Lebl, Matthew L. Clarke
Format: Article
Language:English
Published: MDPI AG 2024-02-01
Series:Molecules
Subjects:
hydroformylation
phosphacycles
homogeneous catalysis
rhodium
in situ spectroscopy
regioselectivity
Online Access:https://www.mdpi.com/1420-3049/29/4/845

Internet

https://www.mdpi.com/1420-3049/29/4/845

Similar Items