Experimental and Theoretical Study on Crown Ether-Appended-Fe(III) Porphyrin Complexes and Catalytic Oxidation Cyclohexene with O<sub>2</sub>

Experimental and Theoretical Study on Crown Ether-Appended-Fe(III) Porphyrin Complexes and Catalytic Oxidation Cyclohexene with O<sub>2</sub>

Modifying non-precious metal porphyrins at the <i>meso</i>-position is sufficient to further improve the ability to activate O<sub>2</sub> and the selectivity of the corresponding redox products. In this study, a crown ether-appended Fe(III) porphyrin complex (FeTC<sub>...

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Bibliographic Details
Main Authors: Xiaodong Li, Ailing Feng, Yanqing Zu, Peitao Liu, Fengbo Han
Format: Article
Language:English
Published: MDPI AG 2023-04-01
Series:Molecules
Subjects:
crown ether-appended Fe(III) porphyrin complexes
catalytic oxidation
cyclohexene
DFT analysis
reaction mechanism
Online Access:https://www.mdpi.com/1420-3049/28/8/3452

Internet

https://www.mdpi.com/1420-3049/28/8/3452

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