Ferromagnetic FeSe2 from a mixed sulphur-selenium complex of iron [Fe{(SePPh2NPPh2S)2N}3] through pyrolysis

Ferromagnetic FeSe2 from a mixed sulphur-selenium complex of iron [Fe{(SePPh2NPPh2S)2N}3] through pyrolysis

Iron (III) thioselenoimidodiphosphinate complex, Fe{(SePPh2NPPh2S)2N}3], was synthesized from the ligand [Ph2P(S)HNP(Se)Ph2], and the complex employed as the combined source of the targeted elements (Fe and Se) to generate orthorhombic FeSe2. This was achieved by thermolysis using a quartz glass tub...

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Bibliographic Details
Main Authors: Temidayo Oyetunde, Martins O. Omorogie, Paul O'Brien
Format: Article
Language:English
Published: Elsevier 2020-04-01
Series:Heliyon
Subjects:
Inorganic chemistry
Iron (III) thioselenoimidodiphosphinate
Ferromagnetic
FeSe2
Single-source precursor
Iron chalcogenides
Online Access:http://www.sciencedirect.com/science/article/pii/S2405844020306083

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http://www.sciencedirect.com/science/article/pii/S2405844020306083

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