Cost-effective equipment for surface pre-treatment for cleaning and excitation of substrates in semiconductor technology

Abstract Abstract This article presents a cost-effective ultraviolet-ozone cleaner (UV/O3 Cleaner) for surface pre-treatment of substrates in the field of semiconductor technology. The cleaner consists of two chambers, the upper one contains the electronics, including the time counter. The lower cha...

Full description

Bibliographic Details
Main Authors: Dominik Weber, Robert Heimburger, Gianina Schondelmaier, Toni Junghans, Annika Zetzl, Dietrich R. T. Zahn, Daniel Schondelmaier
Format: Article
Language:English
Published: Springer 2022-12-01
Series:SN Applied Sciences
Subjects:
Online Access:https://doi.org/10.1007/s42452-022-05219-1
_version_ 1797980452141662208
author Dominik Weber
Robert Heimburger
Gianina Schondelmaier
Toni Junghans
Annika Zetzl
Dietrich R. T. Zahn
Daniel Schondelmaier
author_facet Dominik Weber
Robert Heimburger
Gianina Schondelmaier
Toni Junghans
Annika Zetzl
Dietrich R. T. Zahn
Daniel Schondelmaier
author_sort Dominik Weber
collection DOAJ
description Abstract Abstract This article presents a cost-effective ultraviolet-ozone cleaner (UV/O3 Cleaner) for surface pre-treatment of substrates in the field of semiconductor technology. The cleaner consists of two chambers, the upper one contains the electronics, including the time counter. The lower chamber contains the two UV sterilisation lamps and a UV reflector of anodized aluminium, which confines the area of high Ozone concentration in the area of interest. The device is successfully used for surface cleaning and modification of different materials. To this end, the two important wavelengths 253.7 nm (excitation of organic residues) and 184.9 nm (production of ozone from the atmospheric environment as a strong oxidant) were first detected. The effectiveness of UV/O3 cleaning is demonstrated by improving the properties of indium tin oxide (ITO) for OLED fabrication. The contact angle of water to ITO could be reduced from 90° to 3° and for diiodomethane, it was reduced from 55° to 31° within the 10 min of irradiation. This greatly improved wettability for polar and non-polar liquids can increase the flexibility in further process control. In addition, an improvement in wettability is characterized by measuring the contact angles for titanium dioxide (TiO2) and polydimethylsiloxane (PDMS). The contact angle of water to TiO2 decreased from 70° to 10°, and that of diiodomethane to TiO2 from 54° to 31°. The wettability of PDMS was also greatly increased. Here, the contact angle of water was reduced from 109° to 24° and the contact angle to diiodomethane from 89° to 49°. Article Highlights We report a cost-effective dry-cleaning device for surface cleaning and modification based on ultraviolet-ozone irradiation. Contact angle measurements show an increase of wettability for different materials due to surface modification. The UVO3 pre-treatment improves layer formation and optoelectrical properties of OLEDs.
first_indexed 2024-04-11T05:55:49Z
format Article
id doaj.art-c9064aa06df44bc1aecf9cb653355d54
institution Directory Open Access Journal
issn 2523-3963
2523-3971
language English
last_indexed 2024-04-11T05:55:49Z
publishDate 2022-12-01
publisher Springer
record_format Article
series SN Applied Sciences
spelling doaj.art-c9064aa06df44bc1aecf9cb653355d542022-12-22T04:41:55ZengSpringerSN Applied Sciences2523-39632523-39712022-12-015111110.1007/s42452-022-05219-1Cost-effective equipment for surface pre-treatment for cleaning and excitation of substrates in semiconductor technologyDominik Weber0Robert Heimburger1Gianina Schondelmaier2Toni Junghans3Annika Zetzl4Dietrich R. T. Zahn5Daniel Schondelmaier6University of Applied Science ZwickauUniversity of Applied Science ZwickauUniversity of Applied Science ZwickauUniversity of Applied Science ZwickauUniversity of Applied Science ZwickauSemiconductor Physics, Technische Universität ChemnitzUniversity of Applied Science ZwickauAbstract Abstract This article presents a cost-effective ultraviolet-ozone cleaner (UV/O3 Cleaner) for surface pre-treatment of substrates in the field of semiconductor technology. The cleaner consists of two chambers, the upper one contains the electronics, including the time counter. The lower chamber contains the two UV sterilisation lamps and a UV reflector of anodized aluminium, which confines the area of high Ozone concentration in the area of interest. The device is successfully used for surface cleaning and modification of different materials. To this end, the two important wavelengths 253.7 nm (excitation of organic residues) and 184.9 nm (production of ozone from the atmospheric environment as a strong oxidant) were first detected. The effectiveness of UV/O3 cleaning is demonstrated by improving the properties of indium tin oxide (ITO) for OLED fabrication. The contact angle of water to ITO could be reduced from 90° to 3° and for diiodomethane, it was reduced from 55° to 31° within the 10 min of irradiation. This greatly improved wettability for polar and non-polar liquids can increase the flexibility in further process control. In addition, an improvement in wettability is characterized by measuring the contact angles for titanium dioxide (TiO2) and polydimethylsiloxane (PDMS). The contact angle of water to TiO2 decreased from 70° to 10°, and that of diiodomethane to TiO2 from 54° to 31°. The wettability of PDMS was also greatly increased. Here, the contact angle of water was reduced from 109° to 24° and the contact angle to diiodomethane from 89° to 49°. Article Highlights We report a cost-effective dry-cleaning device for surface cleaning and modification based on ultraviolet-ozone irradiation. Contact angle measurements show an increase of wettability for different materials due to surface modification. The UVO3 pre-treatment improves layer formation and optoelectrical properties of OLEDs.https://doi.org/10.1007/s42452-022-05219-1Surface treatmentContact angle measurementWettabilityOLEDsPDMSTiO2
spellingShingle Dominik Weber
Robert Heimburger
Gianina Schondelmaier
Toni Junghans
Annika Zetzl
Dietrich R. T. Zahn
Daniel Schondelmaier
Cost-effective equipment for surface pre-treatment for cleaning and excitation of substrates in semiconductor technology
SN Applied Sciences
Surface treatment
Contact angle measurement
Wettability
OLEDs
PDMS
TiO2
title Cost-effective equipment for surface pre-treatment for cleaning and excitation of substrates in semiconductor technology
title_full Cost-effective equipment for surface pre-treatment for cleaning and excitation of substrates in semiconductor technology
title_fullStr Cost-effective equipment for surface pre-treatment for cleaning and excitation of substrates in semiconductor technology
title_full_unstemmed Cost-effective equipment for surface pre-treatment for cleaning and excitation of substrates in semiconductor technology
title_short Cost-effective equipment for surface pre-treatment for cleaning and excitation of substrates in semiconductor technology
title_sort cost effective equipment for surface pre treatment for cleaning and excitation of substrates in semiconductor technology
topic Surface treatment
Contact angle measurement
Wettability
OLEDs
PDMS
TiO2
url https://doi.org/10.1007/s42452-022-05219-1
work_keys_str_mv AT dominikweber costeffectiveequipmentforsurfacepretreatmentforcleaningandexcitationofsubstratesinsemiconductortechnology
AT robertheimburger costeffectiveequipmentforsurfacepretreatmentforcleaningandexcitationofsubstratesinsemiconductortechnology
AT gianinaschondelmaier costeffectiveequipmentforsurfacepretreatmentforcleaningandexcitationofsubstratesinsemiconductortechnology
AT tonijunghans costeffectiveequipmentforsurfacepretreatmentforcleaningandexcitationofsubstratesinsemiconductortechnology
AT annikazetzl costeffectiveequipmentforsurfacepretreatmentforcleaningandexcitationofsubstratesinsemiconductortechnology
AT dietrichrtzahn costeffectiveequipmentforsurfacepretreatmentforcleaningandexcitationofsubstratesinsemiconductortechnology
AT danielschondelmaier costeffectiveequipmentforsurfacepretreatmentforcleaningandexcitationofsubstratesinsemiconductortechnology