Polyoxometalatocrown ether: A new type of metallacrown ether based on polyoxometalate

Using chain-like polyethers consisting of two terminal –NH2 groups and (TBA)4[α-Mo8O26] as starting materials, two polyoxometalatocrown ethers were prepared by a cyclization reaction through the formation of Mo≡N triple bonds: (TBA)2[Mo6O17N(o-C6H4OCH2(CH2OCH2)nCH2OC6H4-o)N] (compounds 1, n = 1; 2,...

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Bibliographic Details
Main Authors: Fengping Xiao, Xianggao Meng, Longsheng Wang, Jian Hao, Chunlin Lv, Yongge Wei
Format: Article
Language:English
Published: Tsinghua University Press 2024-06-01
Series:Polyoxometalates
Subjects:
Online Access:https://www.sciopen.com/article/10.26599/POM.2024.9140055