Polyoxometalatocrown ether: A new type of metallacrown ether based on polyoxometalate
Using chain-like polyethers consisting of two terminal –NH2 groups and (TBA)4[α-Mo8O26] as starting materials, two polyoxometalatocrown ethers were prepared by a cyclization reaction through the formation of Mo≡N triple bonds: (TBA)2[Mo6O17N(o-C6H4OCH2(CH2OCH2)nCH2OC6H4-o)N] (compounds 1, n = 1; 2,...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
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Tsinghua University Press
2024-06-01
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| Series: | Polyoxometalates |
| Subjects: | |
| Online Access: | https://www.sciopen.com/article/10.26599/POM.2024.9140055 |
| _version_ | 1827278750887182336 |
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| author | Fengping Xiao Xianggao Meng Longsheng Wang Jian Hao Chunlin Lv Yongge Wei |
| author_facet | Fengping Xiao Xianggao Meng Longsheng Wang Jian Hao Chunlin Lv Yongge Wei |
| author_sort | Fengping Xiao |
| collection | DOAJ |
| description | Using chain-like polyethers consisting of two terminal –NH2 groups and (TBA)4[α-Mo8O26] as starting materials, two polyoxometalatocrown ethers were prepared by a cyclization reaction through the formation of Mo≡N triple bonds: (TBA)2[Mo6O17N(o-C6H4OCH2(CH2OCH2)nCH2OC6H4-o)N] (compounds 1, n = 1; 2, n = 2). As confirmed by single-crystal X-ray diffraction and infrared (IR) studies, the polyoxometalatocrown ether 2 can capture primary ammonium cations in solid state. |
| first_indexed | 2024-04-24T08:06:28Z |
| format | Article |
| id | doaj.art-c9c68d232653427788fd6ed4537aaa75 |
| institution | Directory Open Access Journal |
| issn | 2957-9821 2957-9503 |
| language | English |
| last_indexed | 2024-04-24T08:06:28Z |
| publishDate | 2024-06-01 |
| publisher | Tsinghua University Press |
| record_format | Article |
| series | Polyoxometalates |
| spelling | doaj.art-c9c68d232653427788fd6ed4537aaa752024-04-17T10:43:37ZengTsinghua University PressPolyoxometalates2957-98212957-95032024-06-0132914005510.26599/POM.2024.9140055Polyoxometalatocrown ether: A new type of metallacrown ether based on polyoxometalateFengping Xiao0https://orcid.org/0009-0006-4596-2870Xianggao Meng1Longsheng Wang2Jian Hao3Chunlin Lv4Yongge Wei5https://orcid.org/0000-0001-6105-0288College of Chemistry, Central China Normal University, Wuhan 430079, ChinaCollege of Chemistry, Central China Normal University, Wuhan 430079, ChinaKey Lab of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, ChinaKey Lab of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, ChinaKey Lab of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, ChinaKey Lab of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, ChinaUsing chain-like polyethers consisting of two terminal –NH2 groups and (TBA)4[α-Mo8O26] as starting materials, two polyoxometalatocrown ethers were prepared by a cyclization reaction through the formation of Mo≡N triple bonds: (TBA)2[Mo6O17N(o-C6H4OCH2(CH2OCH2)nCH2OC6H4-o)N] (compounds 1, n = 1; 2, n = 2). As confirmed by single-crystal X-ray diffraction and infrared (IR) studies, the polyoxometalatocrown ether 2 can capture primary ammonium cations in solid state.https://www.sciopen.com/article/10.26599/POM.2024.9140055polyoxometalatescrown etherscrystal structureorganic ammonium cations |
| spellingShingle | Fengping Xiao Xianggao Meng Longsheng Wang Jian Hao Chunlin Lv Yongge Wei Polyoxometalatocrown ether: A new type of metallacrown ether based on polyoxometalate Polyoxometalates polyoxometalates crown ethers crystal structure organic ammonium cations |
| title | Polyoxometalatocrown ether: A new type of metallacrown ether based on polyoxometalate |
| title_full | Polyoxometalatocrown ether: A new type of metallacrown ether based on polyoxometalate |
| title_fullStr | Polyoxometalatocrown ether: A new type of metallacrown ether based on polyoxometalate |
| title_full_unstemmed | Polyoxometalatocrown ether: A new type of metallacrown ether based on polyoxometalate |
| title_short | Polyoxometalatocrown ether: A new type of metallacrown ether based on polyoxometalate |
| title_sort | polyoxometalatocrown ether a new type of metallacrown ether based on polyoxometalate |
| topic | polyoxometalates crown ethers crystal structure organic ammonium cations |
| url | https://www.sciopen.com/article/10.26599/POM.2024.9140055 |
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