Effect of Alkyl Substituents on the Hydrogen Catalytic Osmylation of Cis and Trans 2-Cyclohexene-Cyclohexanol

Effect of Alkyl Substituents on the Hydrogen Catalytic Osmylation of Cis and Trans 2-Cyclohexene-Cyclohexanol

Catalytic osmylation of cis and trans 2-cyclohexene-cyclohexanol (1a) and (1b) are carried out in the presence of N-methyl morpholine-N-oxide. Under the same conditions, only the cis isomer reacted, leading to triol (3). The steric hindrance of the equatorial OH group probably prevents the trans iso...

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Bibliographic Details
Main Authors: Mohammad Raouf Darvich, Jamshid Mohammadi Rovshandeh
Format: Article
Language:English
Published: Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR 1995-12-01
Series:Iranian Journal of Chemistry & Chemical Engineering
Subjects:
osmylation
n-methylmorpholine-n-oxide
cis and trans-2-cyclohexene-cyclohexanol
hydroxylation
Online Access:http://www.ijcce.ac.ir/article_10968_5238a4c9ca54a6c85791b5edc2fbb6f5.pdf

Internet

http://www.ijcce.ac.ir/article_10968_5238a4c9ca54a6c85791b5edc2fbb6f5.pdf

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