Effect of Alkyl Substituents on the Hydrogen Catalytic Osmylation of Cis and Trans 2-Cyclohexene-Cyclohexanol
Catalytic osmylation of cis and trans 2-cyclohexene-cyclohexanol (1a) and (1b) are carried out in the presence of N-methyl morpholine-N-oxide. Under the same conditions, only the cis isomer reacted, leading to triol (3). The steric hindrance of the equatorial OH group probably prevents the trans iso...
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| Format: | Article |
| Language: | English |
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Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR
1995-12-01
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| Series: | Iranian Journal of Chemistry & Chemical Engineering |
| Subjects: | |
| Online Access: | http://www.ijcce.ac.ir/article_10968_5238a4c9ca54a6c85791b5edc2fbb6f5.pdf |
| _version_ | 1828743867877294080 |
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| author | Mohammad Raouf Darvich Jamshid Mohammadi Rovshandeh |
| author_facet | Mohammad Raouf Darvich Jamshid Mohammadi Rovshandeh |
| author_sort | Mohammad Raouf Darvich |
| collection | DOAJ |
| description | Catalytic osmylation of cis and trans 2-cyclohexene-cyclohexanol (1a) and (1b) are carried out in the presence of N-methyl morpholine-N-oxide. Under the same conditions, only the cis isomer reacted, leading to triol (3). The steric hindrance of the equatorial OH group probably prevents the trans isomer from entering into such reaction. Triol (3) was also obtained from the reduction of the diol-ketone (4). |
| first_indexed | 2024-04-13T01:45:42Z |
| format | Article |
| id | doaj.art-ca38a74ab2ae4ee5b1b3da2b88ef5d93 |
| institution | Directory Open Access Journal |
| issn | 1021-9986 1021-9986 |
| language | English |
| last_indexed | 2024-04-13T01:45:42Z |
| publishDate | 1995-12-01 |
| publisher | Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR |
| record_format | Article |
| series | Iranian Journal of Chemistry & Chemical Engineering |
| spelling | doaj.art-ca38a74ab2ae4ee5b1b3da2b88ef5d932022-12-22T03:08:02ZengIranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECRIranian Journal of Chemistry & Chemical Engineering1021-99861021-99861995-12-01142909310968Effect of Alkyl Substituents on the Hydrogen Catalytic Osmylation of Cis and Trans 2-Cyclohexene-CyclohexanolMohammad Raouf Darvich0Jamshid Mohammadi Rovshandeh1Department of Chemistry, Faculty of Science, Tehran University, P.O. Box 14155-6455 Tehran, I.R. IRANDepartment of Chemistry, Faculty of Science, Tehran University, P.O. Box 14155-6455 Tehran, I.R. IRANCatalytic osmylation of cis and trans 2-cyclohexene-cyclohexanol (1a) and (1b) are carried out in the presence of N-methyl morpholine-N-oxide. Under the same conditions, only the cis isomer reacted, leading to triol (3). The steric hindrance of the equatorial OH group probably prevents the trans isomer from entering into such reaction. Triol (3) was also obtained from the reduction of the diol-ketone (4).http://www.ijcce.ac.ir/article_10968_5238a4c9ca54a6c85791b5edc2fbb6f5.pdfosmylationn-methylmorpholine-n-oxidecis and trans-2-cyclohexene-cyclohexanolhydroxylation |
| spellingShingle | Mohammad Raouf Darvich Jamshid Mohammadi Rovshandeh Effect of Alkyl Substituents on the Hydrogen Catalytic Osmylation of Cis and Trans 2-Cyclohexene-Cyclohexanol Iranian Journal of Chemistry & Chemical Engineering osmylation n-methylmorpholine-n-oxide cis and trans-2-cyclohexene-cyclohexanol hydroxylation |
| title | Effect of Alkyl Substituents on the Hydrogen Catalytic Osmylation of Cis and Trans 2-Cyclohexene-Cyclohexanol |
| title_full | Effect of Alkyl Substituents on the Hydrogen Catalytic Osmylation of Cis and Trans 2-Cyclohexene-Cyclohexanol |
| title_fullStr | Effect of Alkyl Substituents on the Hydrogen Catalytic Osmylation of Cis and Trans 2-Cyclohexene-Cyclohexanol |
| title_full_unstemmed | Effect of Alkyl Substituents on the Hydrogen Catalytic Osmylation of Cis and Trans 2-Cyclohexene-Cyclohexanol |
| title_short | Effect of Alkyl Substituents on the Hydrogen Catalytic Osmylation of Cis and Trans 2-Cyclohexene-Cyclohexanol |
| title_sort | effect of alkyl substituents on the hydrogen catalytic osmylation of cis and trans 2 cyclohexene cyclohexanol |
| topic | osmylation n-methylmorpholine-n-oxide cis and trans-2-cyclohexene-cyclohexanol hydroxylation |
| url | http://www.ijcce.ac.ir/article_10968_5238a4c9ca54a6c85791b5edc2fbb6f5.pdf |
| work_keys_str_mv | AT mohammadraoufdarvich effectofalkylsubstituentsonthehydrogencatalyticosmylationofcisandtrans2cyclohexenecyclohexanol AT jamshidmohammadirovshandeh effectofalkylsubstituentsonthehydrogencatalyticosmylationofcisandtrans2cyclohexenecyclohexanol |