Substitution Effect on the Charge Transfer Processes in Organo-Imido Lindqvist-Polyoxomolybdate

Substitution Effect on the Charge Transfer Processes in Organo-Imido Lindqvist-Polyoxomolybdate

Two new aromatic organo-imido polyoxometalates with an electron donor triazole group ([n-Bu4N]2[Mo6O18NC6H4N3C2H2]) (1) and a highly conjugated fluorene ([n-Bu4N]2[Mo6O18NC13H9]) (2) have been obtained. The electrochemical and spectroscopic properties of several organo-imido systems were studied. Th...

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Bibliographic Details
Main Authors: Patricio Hermosilla-Ibáñez, Kerry Wrighton-Araneda, Walter Cañón-Mancisidor, Marlen Gutiérrez-Cutiño, Verónica Paredes-García, Diego Venegas-Yazigi
Format: Article
Language:English
Published: MDPI AG 2018-12-01
Series:Molecules
Subjects:
organoimido
polyoxometalate
charge transfer
electronic properties
TD-DFT
Rhenium
Online Access:http://www.mdpi.com/1420-3049/24/1/44

Internet

http://www.mdpi.com/1420-3049/24/1/44

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