Synthesis and Structures of the Capped and Sandwiched Cobalt Heptamolybdate Polyoxometalate (NH<sub>4</sub>)<sub>6</sub>{[Co(H<sub>2</sub>O)<sub>5</sub>][Mo<sub>7</sub>O<sub>24</sub>][Co(H<sub>2</sub>O)<sub>2</sub>][Mo<sub>7</sub>O<sub>24</sub>][Co(H<sub>2</sub>O)<sub>5</sub>]} · 6 H<sub>2</sub>O and Its Extended Structure (NH<sub>4</sub>)<sub>6</sub>{[Co(H<sub>2</sub>O)<sub>2</sub>]<sub>3</sub>[Mo<sub>7</sub>O<sub>24</sub>]<sub>2</sub>}

Synthesis and Structures of the Capped and Sandwiched Cobalt Heptamolybdate Polyoxometalate (NH<sub>4</sub>)<sub>6</sub>{[Co(H<sub>2</sub>O)<sub>5</sub>][Mo<sub>7</sub>O<sub>24</sub>][Co(H<sub>2</sub>O)<sub>2</sub>][Mo<sub>7</sub>O<sub>24</sub>][Co(H<sub>2</sub>O)<sub>5</sub>]} · 6 H<sub>2</sub>O and Its Extended Structure (NH<sub>4</sub>)<sub>6</sub>{[Co(H<sub>2</sub>O)<sub>2</sub>]<sub>3</sub>[Mo<sub>7</sub>O<sub>24</sub>]<sub>2</sub>}

Two polyoxometalate-based compounds containing the heptamolybdate anion and cobalt(II) have been synthesized, structurally characterized via single-crystal X-ray diffraction and spectroscopically analyzed with solid-state UV–Vis–NIR. The first crystal structure presented is a capped- and sandwich-st...

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Bibliographic Details
Main Authors: Matthieu R. Spriet, Matthew J. Polinski, Brandon Q. Mercado, Eric M. Villa
Format: Article
Language:English
Published: MDPI AG 2022-08-01
Series:Crystals
Subjects:
polyoxometalates
heptamolybdate
cobalt
crystal structures
Online Access:https://www.mdpi.com/2073-4352/12/9/1201

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https://www.mdpi.com/2073-4352/12/9/1201

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