Exceptionally Long Covalent CC Bonds—A Local Vibrational Mode Study

Exceptionally Long Covalent CC Bonds—A Local Vibrational Mode Study

For decades one has strived to synthesize a compound with the longest covalent C−C bond applying predominantly steric hindrance and/or strain to achieve this goal. On the other hand electronic effects have been added to the repertoire, such as realized in the electron deficient ethane radical cation...

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Bibliographic Details
Main Authors: Alexis Antoinette Ann Delgado, Alan Humason, Robert Kalescky, Marek Freindorf, Elfi Kraka
Format: Article
Language:English
Published: MDPI AG 2021-02-01
Series:Molecules
Subjects:
longest CC bonds
vibrational spectroscopy
local mode theory
local mode force constants
steric versus electronic effects
Online Access:https://www.mdpi.com/1420-3049/26/4/950

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https://www.mdpi.com/1420-3049/26/4/950

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