Mechanistic Studies on Rhodium-Catalyzed Chemoselective Cycloaddition of Ene-Vinylidenecyclopropanes: Water-Assisted Proton Transfer

Rhodium-catalyzed cycloaddition reactions are a powerful tool for the construction of polycyclic compounds. Combined experimental and DFT studies were used to investigate the temperature-controlled chemoselectivity of cationic rhodium-catalyzed intramolecular cycloaddition reactions of ene-vinyliden...

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Bibliographic Details
Main Authors: Ziqi Yu, Min Shi, Yin Wei
Format: Article
Language:English
Published: MDPI AG 2024-02-01
Series:Molecules
Subjects:
Online Access:https://www.mdpi.com/1420-3049/29/5/1085