Dynamic behavior of rearranging carbocations – implications for terpene biosynthesis

This review describes unexpected dynamical behaviors of rearranging carbocations and the modern computational methods used to elucidate these aspects of reaction mechanisms. Unique potential energy surface topologies associated with these rearrangements have been discovered in recent years that are...

Full description

Bibliographic Details
Main Authors: Stephanie R. Hare, Dean J. Tantillo
Format: Article
Language:English
Published: Beilstein-Institut 2016-02-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
Online Access:https://doi.org/10.3762/bjoc.12.41