Tuning of SnS Thin Film Conductivity on Annealing in an Open Air Environment for Transistor Application

The study aimed at enhancement and optimisation of SnS conductivity via annealing for field effect transistor’s semiconductor channel layer application. Interstitials and vacancies in SnS films are known to cause carrier traps which limit charge carriers and hence limit the achievement of the thresh...

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Main Authors: Thomas Daniel, Uno Uno, Kasim Isah, Umaru Ahmadu
Format: Article
Language:English
Published: V.N. Karazin Kharkiv National University Publishing 2020-04-01
Series:East European Journal of Physics
Subjects:
Online Access:https://periodicals.karazin.ua/eejp/article/view/15541
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author Thomas Daniel
Uno Uno
Kasim Isah
Umaru Ahmadu
author_facet Thomas Daniel
Uno Uno
Kasim Isah
Umaru Ahmadu
author_sort Thomas Daniel
collection DOAJ
description The study aimed at enhancement and optimisation of SnS conductivity via annealing for field effect transistor’s semiconductor channel layer application. Interstitials and vacancies in SnS films are known to cause carrier traps which limit charge carriers and hence limit the achievement of the threshold voltage for a field effect transistor operation. Tuning of SnS conductivity for transistor application is of emerging interest for novel device operation. SnS thin film semiconductors of 0.4  thickness were deposited using Aerosol assisted chemical vapour deposition and annealed in open air at annealing temperatures of150, 200, 250, 300 and 350 . Variation of the annealing temperature from 150 through 250  enhances the crystallinity of the annealed thin film samples by increasing the number of crystallites of the annealed films which is also buttress by the decreasing values of FWHM. However a further decrease in crystallite size at higher annealing temperature of 300 to 350  was observed which could be attributed to the fragmentation of clusters of crystallites at higher annealing temperature. Increase in annealing temperature increases grain size leading to the reduction in grain boundaries and potential barrier thereby changing the structure and phase of the films which in essence affects the electrical conductivity of the SnS thin films. The films annealed at 250 exhibited optimum conductivity. The average hall coefficients of the samples deposited at 150 to 250  were positive which indicates that the films annealed at this temperature range are of p type conduction while the average hall coefficients of the samples deposited at 300 and 350  were negative indicating that the films are of n type conduction. The conductivity change is essential for the use of SnS as a semiconductor channel layer especially in a field effect transistor where the device can be tuned to work as a p type or n type semiconductor channel layer.
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spelling doaj.art-cc84409801684b09bffd2c3956fbd22e2022-12-21T17:00:48ZengV.N. Karazin Kharkiv National University PublishingEast European Journal of Physics2312-43342312-45392020-04-0129410310.26565/2312-4334-2020-2-0815541Tuning of SnS Thin Film Conductivity on Annealing in an Open Air Environment for Transistor ApplicationThomas Daniel0Uno Uno1Kasim Isah2Umaru Ahmadu3Department of Physics/Geology/Geophysics, Alex Ekwueme-Federal University Ndufu-Alike Ikwo, Ebonyi state, Nigeria; Department of Physics, Federal University of Technology Minna, Minna, Niger state, NigeriaDepartment of Physics, Federal University of Technology Minna, Minna, Niger state, NigeriaDepartment of Physics, Federal University of Technology Minna, Minna, Niger state, NigeriaDepartment of Physics, Federal University of Technology Minna, Minna, Niger state, NigeriaThe study aimed at enhancement and optimisation of SnS conductivity via annealing for field effect transistor’s semiconductor channel layer application. Interstitials and vacancies in SnS films are known to cause carrier traps which limit charge carriers and hence limit the achievement of the threshold voltage for a field effect transistor operation. Tuning of SnS conductivity for transistor application is of emerging interest for novel device operation. SnS thin film semiconductors of 0.4  thickness were deposited using Aerosol assisted chemical vapour deposition and annealed in open air at annealing temperatures of150, 200, 250, 300 and 350 . Variation of the annealing temperature from 150 through 250  enhances the crystallinity of the annealed thin film samples by increasing the number of crystallites of the annealed films which is also buttress by the decreasing values of FWHM. However a further decrease in crystallite size at higher annealing temperature of 300 to 350  was observed which could be attributed to the fragmentation of clusters of crystallites at higher annealing temperature. Increase in annealing temperature increases grain size leading to the reduction in grain boundaries and potential barrier thereby changing the structure and phase of the films which in essence affects the electrical conductivity of the SnS thin films. The films annealed at 250 exhibited optimum conductivity. The average hall coefficients of the samples deposited at 150 to 250  were positive which indicates that the films annealed at this temperature range are of p type conduction while the average hall coefficients of the samples deposited at 300 and 350  were negative indicating that the films are of n type conduction. The conductivity change is essential for the use of SnS as a semiconductor channel layer especially in a field effect transistor where the device can be tuned to work as a p type or n type semiconductor channel layer.https://periodicals.karazin.ua/eejp/article/view/15541sns thin filmannealingconductivitygrain sizetransistorsemiconductor
spellingShingle Thomas Daniel
Uno Uno
Kasim Isah
Umaru Ahmadu
Tuning of SnS Thin Film Conductivity on Annealing in an Open Air Environment for Transistor Application
East European Journal of Physics
sns thin film
annealing
conductivity
grain size
transistor
semiconductor
title Tuning of SnS Thin Film Conductivity on Annealing in an Open Air Environment for Transistor Application
title_full Tuning of SnS Thin Film Conductivity on Annealing in an Open Air Environment for Transistor Application
title_fullStr Tuning of SnS Thin Film Conductivity on Annealing in an Open Air Environment for Transistor Application
title_full_unstemmed Tuning of SnS Thin Film Conductivity on Annealing in an Open Air Environment for Transistor Application
title_short Tuning of SnS Thin Film Conductivity on Annealing in an Open Air Environment for Transistor Application
title_sort tuning of sns thin film conductivity on annealing in an open air environment for transistor application
topic sns thin film
annealing
conductivity
grain size
transistor
semiconductor
url https://periodicals.karazin.ua/eejp/article/view/15541
work_keys_str_mv AT thomasdaniel tuningofsnsthinfilmconductivityonannealinginanopenairenvironmentfortransistorapplication
AT unouno tuningofsnsthinfilmconductivityonannealinginanopenairenvironmentfortransistorapplication
AT kasimisah tuningofsnsthinfilmconductivityonannealinginanopenairenvironmentfortransistorapplication
AT umaruahmadu tuningofsnsthinfilmconductivityonannealinginanopenairenvironmentfortransistorapplication