Free volumes in mixed-tacticity poly(3-hydroxybutyrate) determined by viscosimetry and their correlations with structural features and mechanical properties

The viscosities of poly(3-hydroxybutyrate) (PHB) with mixed tacticities were determined as functions of temperature and shearing rate via plate–plate viscosimetry, and fitted by a combined Herschel–Bulkley–Cross–Doolittle model while applying Carvalho et al.’s single-point correction. They were comp...

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Bibliographic Details
Main Authors: Van Opdenbosch Daniel, Kretschmer Martin, Lieleg Oliver, Zollfrank Cordt
Format: Article
Language:English
Published: De Gruyter 2022-07-01
Series:Applied Rheology
Subjects:
Online Access:https://doi.org/10.1515/arh-2022-0125