[n-Bu2 NH2]3[SnPh3(SeO4)2]: the first triorganotin(IV) complex with terminally coordinated selenato ligands

[n-Bu2 NH2]3[SnPh3(SeO4)2]: the first triorganotin(IV) complex with terminally coordinated selenato ligands

The reaction of SeO4 H2 and SnPh3 OH in the presence of n-Bu2 NH led to the formation of [(n-Bu2 NH2)]3[SnPh3(SeO4)2] (1), which crystallizes in the orthorhombic space group P21 21 21 with Z=4, a=16.2509(7) Å, b=17.2412(8) Å, c=17.6881(5) Å, and V=4955.9(3) Å3. The structure of the novel trianion of...

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Bibliographic Details
Main Authors: Diallo Waly, Diop Libasse, Plasseraud Laurent, Cattey Hélène
Format: Article
Language:English
Published: De Gruyter 2014-07-01
Series:Main Group Metal Chemistry
Subjects:
hydrogen bonding
selenate
triphenyltin
x-ray crystallography
3d supramolecular network
Online Access:https://doi.org/10.1515/mgmc-2014-0011

Internet

https://doi.org/10.1515/mgmc-2014-0011

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