Synthesis, crystal structure and properties of tetrakis(pyridine-3-carbonitrile)dithiocyanatoiron(II) and of diaquabis(pyridine-3-carbonitrile)dithiocyanatoiron(II) pyridine-3-carbonitrile monosolvate

Synthesis, crystal structure and properties of tetrakis(pyridine-3-carbonitrile)dithiocyanatoiron(II) and of diaquabis(pyridine-3-carbonitrile)dithiocyanatoiron(II) pyridine-3-carbonitrile monosolvate

The reaction of iron thiocyanate with 3-cyanopyridine (C6H4N2) leads to the formation of two compounds with the composition [Fe(NCS)2(C6H4N2)4] (1) and [Fe(NCS)2(C6H4N2)2(H2O)2]·2C6H4N2 (2). The asymmetric unit of 1 consists of one iron cation, two thiocyanate anions and four 3-cyanopyridine ligands...

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Bibliographic Details
Main Authors: Christian Näther, Asmus Müller-Meinhard, Inke Jess
Format: Article
Language:English
Published: International Union of Crystallography 2023-11-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
iron thiocyanate
3-cyanopyridine
thermal properties
ir spectrum
Online Access:http://scripts.iucr.org/cgi-bin/paper?S205698902300909X

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http://scripts.iucr.org/cgi-bin/paper?S205698902300909X

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