Stabilization of Pancake Bonding in (TCNQ)2.− Dimers in the Radical‐Anionic Salt (N−CH3−2‐NH2−5Cl−Py)(TCNQ)(CH3CN) Solvate and Antiferromagnetism Induction

Stabilization of Pancake Bonding in (TCNQ)2.− Dimers in the Radical‐Anionic Salt (N−CH3−2‐NH2−5Cl−Py)(TCNQ)(CH3CN) Solvate and Antiferromagnetism Induction

Abstract We report a new antiferromagnetic radical‐anion salt (RAS) formed from 7,7,8,8‐tetracyanquinonedimethane (TCNQ) anion and 2‐amino‐5‐chloro‐pyridine cation with the composition of (N−CH3−2‐NH2−5Cl−Py)(TCNQ)(CH3CN). The crystallographic data indicates the formation of (TCNQ)2.− radical‐anion...

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Bibliographic Details
Main Authors: Dr. Tetiana N. Starodub, Dr. Erik Čižmár, Andrii Kliuikov, Prof. Vladimir A. Starodub, Prof. Alexander Feher, Dr. Mariana Kozlowska
Format: Article
Language:English
Published: Wiley-VCH 2019-07-01
Series:ChemistryOpen
Subjects:
charge transfer processes
crystal engineering
density functional calculations
magnetic properties
radical ions
Online Access:https://doi.org/10.1002/open.201900179

Internet

https://doi.org/10.1002/open.201900179

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