New copper(II) μ-alkoxo-μ-carboxylato double-bridged complexes as models for the active site of catechol oxidase: synthesis, spectral characterization and DFT calculations
A series of four copper(II) μ-Alkoxo-μ-carboxylato double bridged complexes, [{Cu2(L)}2][(μ–O2C–CO2] 1, [{Cu2(L)}2(μ–O2C–(CH2)CO2] 2, [{Cu2(L)}2(μ–O2C–CH2–CO2] 3 and [{Cu2(L)}2(μ–O2C–C6H4–CO2] 4 (H3L = 4-bromo-2-((E)-((3-(((E)-5-chloro-2-hydroxybenzylidene) amino)-2-hydroxypropyl) imino) methyl)-6-m...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Elsevier
2022-05-01
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| Series: | Heliyon |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2405844022006612 |