Experimental and theoretical insights in the alkene–arene intramolecular π-stacking interaction

Experimental and theoretical insights in the alkene–arene intramolecular π-stacking interaction

Chiral acrylic esters derived from biomass were developed as models to have a better insight in the aryl–vinyl π-stacking interactions. Quantum chemical calculations, NMR studies and experimental evidences demonstrated the presence of equilibriums of at least four different conformations: π-stacked...

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Bibliographic Details
Main Authors: Valeria Corne, Ariel M. Sarotti, Carmen Ramirez de Arellano, Rolando A. Spanevello, Alejandra G. Suárez
Format: Article
Language:English
Published: Beilstein-Institut 2016-07-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
acrylic esters
asymmetric synthesis
biomass
conformational equilibrium
π-stacking interaction
Online Access:https://doi.org/10.3762/bjoc.12.158

Internet

https://doi.org/10.3762/bjoc.12.158

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