α-Diimine Ni-Catalyzed Ethylene Polymerizations: On the Role of Nickel(I) Intermediates

α-Diimine Ni-Catalyzed Ethylene Polymerizations: On the Role of Nickel(I) Intermediates

Nickel(II) complexes with bidentate <i>N</i>,<i>N</i>-α-diimine ligands constitute a broad class of promising catalysts for the synthesis of branched polyethylenes via ethylene homopolymerization. Despite extensive studies devoted to the rational design of new Ni(II) α-diimin...

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Bibliographic Details
Main Authors: Igor E. Soshnikov, Nina V. Semikolenova, Konstantin P. Bryliakov, Evgenii P. Talsi
Format: Article
Language:English
Published: MDPI AG 2021-11-01
Series:Catalysts
Subjects:
monovalent nickel
α-diimines
branched polyethylene
NMR
EPR
active species
Online Access:https://www.mdpi.com/2073-4344/11/11/1386

Internet

https://www.mdpi.com/2073-4344/11/11/1386

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