The Reaction Mechanism of the Cu(I) Catalyzed Alkylation of Heterosubstituted Alkynes
Alkynes may be regioselectively alkylated to alkenes by organocopper reagents in a reaction known as “carbocupration”, where an alkylCu(I) binds to the alkyne and transfers its organic moiety to one of the alkyne carbon atoms. Alkynes hetero-substituted with third-row elements yield alkenes with a r...
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| Format: | Article |
| Language: | English |
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MDPI AG
2022-12-01
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| Series: | Catalysts |
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| Online Access: | https://www.mdpi.com/2073-4344/13/1/17 |