Synthesis of highly substituted allenylsilanes by alkylidenation of silylketenes

Background<p>Allenylsilanes are useful intermediates in organic synthesis. An attractive, convergent but little used approach for their synthesis is the alkylidenation of stable silylketenes. Reactions thus far have been limited to the use of unsubstituted silylketenes (or equivalents) with st...

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Bibliographic Details
Main Authors: Stephen P. Marsden, Pascal C. Ducept
Format: Article
Language:English
Published: Beilstein-Institut 2005-08-01
Series:Beilstein Journal of Organic Chemistry
Online Access:https://doi.org/10.1186/1860-5397-1-5