Pd-Catalyzed Carbonyl Insertion Coupling Reactions of a Hypervalent Iodoheterocycle with Alcohols and Amines

Pd-Catalyzed Carbonyl Insertion Coupling Reactions of a Hypervalent Iodoheterocycle with Alcohols and Amines

The palladium-catalyzed cross-coupling carbonyl insertion reaction between 3,7-bis(N,N-dimethylamino)-10H-dibenz[b,e]iodinium iodide (1) and alcohols or amines 2 is described. Some new amides and esters 3 containing an active iodo functional group have been prepared in 65-91% yields.

Bibliographic Details
Main Authors: Yong-Min Liang, Yong-Xiang Ma, Shengj-Jun Luo
Format: Article
Language:English
Published: MDPI AG 2005-01-01
Series:Molecules
Subjects:
Cross-coupling
hypervalent iodoheterocycle
carbonyl insertion
amides
esters
Online Access:http://www.mdpi.com/1420-3049/10/1/238/

Internet

http://www.mdpi.com/1420-3049/10/1/238/

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