Umpolung reactivity of strained C–C σ-bonds without transition-metal catalysis

Abstract Umpolung is an old and important concept in organic chemistry, which significantly expands the chemical space and provides unique structures. While, previous research focused on carbonyls or imine derivatives, the umpolung reactivity of polarized C–C σ-bonds still needs to explore. Herein,...

Full description

Bibliographic Details
Main Authors: Dachang Bai, Xiuli Guo, Xinghua Wang, Wenjie Xu, Ruoshi Cheng, Donghui Wei, Yu Lan, Junbiao Chang
Format: Article
Language:English
Published: Nature Portfolio 2024-04-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-024-47169-9